https://www.selleckchem.com/Proteasome.html We report a study of the reactions of pure metal clusters Nbn- with dioxygen in the gas phase. It is found that the presence of low-concentration dioxygen reactants results in oxygen-addition products, whereas sufficient high-concentration dioxygen enables oxygen-etching reactions giving rise to molecular niobium oxides. Interestingly, in the presence of a suitable gas flow rate of an intermediate dioxygen concentration, a highly selective product Nb11O15- shows up in the mass spectra. Utilizing density functional theory (DFT) calculations, we have discussed the reactivities of Nbn- (3 ≤ n ≤ 14) clusters with oxygen, and unveiled the reasonable stability of Nb11O15- pertaining to its unique geometric structure with a D5h Nb@Nb10 core fully protected by 15 bridge-oxygen atoms. The oxygen-passivated Nb@Nb10O15- cluster exhibits a large HOMO-LUMO gap (1.46 eV) and effective multicenter bonds with remarkable superatom orbitals for all the 26 valence electrons of the Nb@Nb10 core corresponding to well-staggered energy levels. We illustrate the superatomic features in the Nb@Nb10 metallic core for which the adaptive natural density partitioning (AdNDP) analysis unveils thirteen 11c-2e bonds. Among them, one of the 11c-2e bonds accounts for the superatomic S orbital, three bonds correspond to superatomic P orbitals, another five display vivid D orbital characteristics, and the remaining four 11c-2e bonds are assigned to F orbital features. In addition, the net atomic charge of the center Nb atom is as high as -0.804 |e| rendering core-shell electrostatic interactions and the shielding effect of the Nb10O15 shell.The essential role of boronic esters in controlling both the direction and selectivity of chemical reactions as well as their significant function in catalytic activity have been demonstrated for industrially important processes. The specific interaction analyses of the monosaccharide GlcNH2 with boric acid are of interes