Environmental concerns have been raised regarding the intense contamination of water resources. Currently, numerous contaminants that reach water bodies are not efficiently removed by conventional water treatment methods. Therefore, there arises the need for development and optimization of efficient treatment methods for the removal of such recalcitrant contaminants. Given the circumstances, the present study aims to use of advanced oxidative processes for dye degradation. For this purpose, copper and zinc doped cobalt ferrites were synthesized by coprecipitation, targeting the degradation of methylene blue dye.  https://www.selleckchem.com/products/jib-04.html  The photocatalysts were characterized by XRD, WD-XRF, FE-SEM, N2 physisorption isotherms, UV-Vis diffuse reflectance spectroscopy, molecular fluorescence spectroscopy and zeta potential. According to the investigation of the degradation mechanism, the holes and hydroxyl radicals were mainly responsible for the dye's degradation. The obtained photocatalysts displayed promising results with up to 99% of dye degradation, employing conventional visible LED lamps, making the practical use of the catalyst highly viable, as well as the economic matters. Additionally, the synthesized materials' magnetic properties allowed total and efficient separation of the catalyst for its reutilization up to 4 cycles, with no decrease in photocatalytic activity and with low leaching of iron ions to solution.Carcinogenic polycyclic aromatic hydrocarbons (PAHs) are widespread in the environment. In this study, the removal of PAHs from aqueous media was assessed using samples of clinoptilolite, a natural zeolite, pre-treated with 1 mol/L of NaCl, (Na pre-treated clinoptilolite, NC). Samples (10 g) of NC were separately modified with 5, 2, 2, and 20-mmol/L solutions of cetylpyridinium chloride (CPC), didodecyldimethyl ammonium bromide (DDAB), hexadecyltrimethylammonium bromide (HDTMA), and tetramethyl ammonium chloride (TMA) surfactants as potential cost-effective adsorbents. The kinetics, optimal sorbent dosage, and competitive effects were evaluated through batch adsorption tests using deionised water spiked with five PAHs (anthracene (50 μg/L), fluoranthene (100 μg/L), fluorene (100 μg/L), phenanthrene (100 μg/L), and pyrene (100 μg/L)). The surfactant non-modified (NC) and TMA-MC (modified clinoptilolite) exhibited PAH removal of NC). With a solidliquid ratio of 1200, over 90%, 80%, and 70% of the anthracene, fluoranthene, and pyrene were adsorbed by the CPC-MC, DDAB-MC, and HDTMA-MC, respectively.Environmental sustainability criteria and rising energy demands, exhaustion of conventional resources of energy followed by environmental degradation due to abrupt climate changes have shifted the attention of scientists to seek renewable sources of green and clean energy for sustainable development. Bioenergy is an excellent alternative since it can be applied for several energy-requirements after utilizing suitable conversion methodology. This review elucidates all aspects of biofuels (bioethanol, biodiesel, and butanol) and their sustainability criteria. The principal focus is on the latest developments in biofuel production chiefly stressing on the role of nanotechnology. A plethora of investigations regarding the emerging techniques for process improvement like integration methods, less energy-intensive distillation techniques, and bioengineering of microorganisms are discussed. This can assist in making biofuel-production in a real-world market more economically and environmentally viable.Wildlife crossing structures can provide safe passage for wildlife across transportation corridors, and can help mitigate the effects of highways and exclusion fencing on wildlife. Due to their costs, wildlife crossing structures are usually installed sparsely and at strategic locations along transportation networks. Alternatively, non-wildlife underpasses (i.e. conventional underpasses for human and domestic animal use) are usually abundant along major infrastructure corridors and could potentially provide safe crossing opportunities for wildlife. To investigate this, we monitored the use of 40 non-wildlife underpasses by roe deer (Capreolus capreolus), and moose (Alces alces) in south-central Sweden. We found that roe deer and moose use non-wildlife underpasses, and prefer underpasses that are at least 11.5 m wide and 5 m tall. Furthermore, roe deer used structures that had little human co-use and were in locations where the forest cover differed on both sides of the highway. In most cases, roe deer and moose were detected within 50 m of the underpass more than they were detected crossing under them. This suggests that animals often approach underpasses without crossing under them, however modifications to underpass design may improve non-wildlife underpass use. We recommend non-wildlife underpasses at gravel and minor roads, particularly those with little human co-use and with variable forest cover on both sides of the highway, be built wider than 11.5 m and taller than 5 m.Toxicity and poor adherence to treatment that favors the generation of resistance in the Leishmania parasites highlight the need to develop better alternatives. Here, we evaluated the in vitro effectiveness of hydrazone derived from chromanes 2-(2,3-dihydro-4H-1-benzothiopyran-4-ylidene) hydrazide (TC1) and 2-(2,3-dihydro-4H-1-benzopyran-4-ylidene) hydrazide (TC2) and the mixture of triterpene saponin hederagenin-3-O-(3,4-O-diacetyl-ß-D-xylopyranosyl-(1à3)-a-L- rhamnopyranosyl-(1à2)-a-L-arabinofuranoside, hederagenin-3-O-(3,4-O-diacetyl-a-L- arabinopyranosyl-(1à3)-a-L-rhamnopyranosyl-(1à2)-a-L-arabinofuranoside and, hederagenin-3-O-(4-O-acetyl-ß-D-xylopyranosyl-(1à3)-a-L-rhamnopyranosyl-(1à2)-a-L-arabinofuranoside from Sapindus saponaria (SS) on L. braziliensis and L. pifanoi. Mixtures of TC1 or TC2 with saponin were formulated for topical application and the therapeutic effectiveness was evaluated in the model for cutaneous leishmaniasis (CL) in golden hamster. The mode of action of these compounds was testeacrophage. The results suggest that the combination of TC1 and TC2 with SS in a 11 ratio is capable of curing CL in hamsters. This effect may be due to the ability of these compounds to affect parasite survival and the ability to infect new cells.