https://www.selleckchem.com/products/trolox.html al communities.Frictional heat has been widely used in various polymer-based advanced manufacturing. The fundamental understanding of the thermodynamics of the interfacial friction of polymer bulk materials can help to avoid compromising the process controllability. In this work, we have performed united-atom molecular dynamics (MD) simulations to reveal the interfacial friction heating mechanism of amorphous polyethene (PE) in both the single sliding friction (SSF) and reciprocating sliding friction (RSF) modes. Different from the traditional view that the plastic deformation was the primary source of heat generation, the RSF process with no apparent plastic deformation in this work shows a better heat generation performance than SSF, where plastic deformation dominated the friction process. Our analysis uncovers that the mechanism of the interfacial friction heating enhancement in RSF can be attributed to the concentrated high-frequency chain motion related to molecular rearrangement, which is not clearly related to the deformation degree.Dielectric spectroscopy was employed, for the first time, to monitor the formation process of silica nanoparticles in a nonionic surfactant-based microemulsion in situ and in real time. Two dominant relaxations were observed in the frequency range of 1 MHz-3 GHz during this process. The relaxation at the lower frequency range was confirmed to be mainly ascribed to interfacial polarization, whose relaxation parameters, together with the electrical property of the synthesis system, were used to characterize the evolution of this dynamic formation process. Four evolution stages are distinctively revealed, including an induction stage, a nucleation dominant stage, an early particle growth stage, and a late growth stage. The dynamic features at each evolution stages were discussed in terms of the dielectric characteristics of the system. It is strongly suggested that dielectric spectros